Title

Refining Boron-Iodane Exchange to Access Versatile Arylation Reagents.

Published In

Chemical Communications (cambridge, England)

Document Type

Citation

Publication Date

1-4-2022

Abstract

Aryl (Mes) iodonium salts, which are multifaceted aryl transfer reagents, are synthesized boron-iodane exchange. Modification to both the nucleophilic (aryl boron) and electrophilic (mesityl-λ-iodane) reaction components results in improved yield and faster reaction time compared to previous conditions. Mechanistic studies reveal a pathway that is more like transmetallation than SAr.

Rights

© 2022 The Royal Society of Chemistry

DOI

10.1039/d1cc06341c

Persistent Identifier

https://archives.pdx.edu/ds/psu/36990

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