First Advisor

Gary L. Gard

Term of Graduation

Fall 1981

Date of Publication

11-18-1981

Document Type

Thesis

Degree Name

Master of Science (M.S.) in Chemistry

Department

Chemistry

Language

English

Subjects

Organic chemistry, Chromium

DOI

10.15760/etd.3091

Physical Description

1 online resource (3, 112 pages)

Abstract

Pure chromium oxide trifluoride was prepared for the first time by reaction of CrO₃ and ClF with subsequent multiple fluorine treatments at 120°C. On the basis of its infrared spectrum, the purple CrOF₃ was assigned as a fluorine-bridged polymer with terminal oxygen groups. Chromium oxide trifluoride was found to be stable to 300°C, where it decomposes with the loss of oxygen to CrF₃.

Rights

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Comments

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Persistent Identifier

http://archives.pdx.edu/ds/psu/18059

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