Picture of a Chelate in Exchange: The Crystal Structure of NaHoDOTMA, a 'Semi'-Hydrated Chelate

Authors

Katherine M. Payne, Portland State University
Edward J. Valente, University of Portland
Silvio Aime, University of TorinoFollow
Mauro Botta, Università del Piemonte Orientale
Mark Woods, Portland State UniversityFollow

Sponsor

EB-11687 United States EB NIBIB NIH HHS; R21 EB011687 United States EB NIBIB NIH HHS

Published In

Chemical Communications

Document Type

Post-Print

Publication Date

2-12-2013

Subjects

Chelating Agents -- Chemistry, Organometallic Compounds -- Chemistry, Crystallography

Abstract

Crystallography generally only provides static structural information. This can render it an ineffective technique for probing dynamic solution state processes. A crystal of HoDOTMA affords unique structures that effectively represent that of a lanthanide tetra-acetate chelate mid-way through the water exchange process.

Description

DOI: 10.1039/C3CC38814J

Published by the Royal Society of Chemistry. The final edited version can be found at http://pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc38814j#!divAbstract

Supplementary Materials http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3620659/

DOI

10.1039/c3cc38814j

Persistent Identifier

http://archives.pdx.edu/ds/psu/11015

Citation Details

Payne, K., Valente, E., Aime, S., Botta, M., & Woods, M. (2013). Picture of a chelate in exchange: the crystal structure of NaHoDOTMA, a 'semi'-hydrated chelate. Chemical Communications (Cambridge, England), 49(23), 2320-2322. doi:10.1039/c3cc38814j