Portland State University. Department of Chemistry
Gary L. Gard
Date of Award
Master of Science (M.S.) in Chemistry
1 online resource (115 p.)
Esters, Fluorine compounds
Reactions of different alcohols with 2-hydroxy - 1- trifluoromethyl -1,2,2-trifluoroethanesulfonic acid sultone were studied. Six new esters were prepared: C6F5OC(O)CF(CF3)SO2F, CH3CH2OC(O)CF(CF3)SO2F, CF3CH2OC(O)CF(CF3)SO2F, (CF3)2CHOC(O)CF(CF3)SO2F, CH2=CHCH20C(O)CF(CF3)SO2F, (CH2OC(O)CF(CF3)SO2F)2. Analytical data, infrared, nmr and mass spectra are presented supporting the proposed structures for these new compounds.
Schaff, Jilla, "Fluorinated esters : synthesis and identification" (1988). Dissertations and Theses. Paper 3921.