An Improved and Versatile Synthetic Route to 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane

Authors

Mark Woods, Portland State UniversityFollow
A. Dean Sherry, University of Texas Southwestern Medical CenterFollow

Published In

Inorganica Chimica Acta

Document Type

Citation

Publication Date

7-2003

Abstract

A new and effective synthetic pathway to 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane (1) has been developed. Beginning from salicylic acid, this synthetic pathway involves five high yielding steps to afford the macrocycle 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane-3,10-dione. Reduction of this macrocycle afforded the dioxadiaza crown 1 with an overall yield of 60%.

A new and effective synthetic pathway to 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane (1) has been developed. Beginning from salicylic acid, this synthetic pathway involves five high yielding steps to afford the macrocycle 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane-3,10-dione. Reduction of this macrocycle afforded the dioxadiaza crown 1 with an overall yield of 60%.

Rights

Copyright © 2021 Elsevier B.V.

Description

*At the time of publication, Mark Woods was affiliated with the University of Texas at Dallas.

Locate the Document

https://doi.org/10.1016/S0020-1693(03)00201-9

DOI

10.1016/S0020-1693(03)00201-9

Persistent Identifier

https://archives.pdx.edu/ds/psu/36503

Citation Details

Woods, M., & Sherry, A. D. (2003). An improved and versatile synthetic route to 6, 7: 13, 14-dibenzo-1, 8, 4, 11-dioxadiazacyclotetradecane. Inorganica chimica acta, 351, 395-398.