Title

An Improved and Versatile Synthetic Route to 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane

Published In

Inorganica Chimica Acta

Document Type

Citation

Publication Date

7-2003

Abstract

A new and effective synthetic pathway to 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane (1) has been developed. Beginning from salicylic acid, this synthetic pathway involves five high yielding steps to afford the macrocycle 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane-3,10-dione. Reduction of this macrocycle afforded the dioxadiaza crown 1 with an overall yield of 60%.

A new and effective synthetic pathway to 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane (1) has been developed. Beginning from salicylic acid, this synthetic pathway involves five high yielding steps to afford the macrocycle 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane-3,10-dione. Reduction of this macrocycle afforded the dioxadiaza crown 1 with an overall yield of 60%.

Rights

Copyright © 2021 Elsevier B.V.

Description

*At the time of publication, Mark Woods was affiliated with the University of Texas at Dallas.

DOI

10.1016/S0020-1693(03)00201-9

Persistent Identifier

https://archives.pdx.edu/ds/psu/36503

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