First Advisor

Gary L. Gard

Term of Graduation

Spring 1984

Date of Publication

5-17-1984

Document Type

Thesis

Degree Name

Master of Science (M.S.) in Chemistry

Department

Chemistry

Language

English

Subjects

Hypochlorites, Chemistry -- Research -- United States, Sulfonic acids

DOI

10.15760/etd.5252

Physical Description

1 online resource (v, 110 pages)

Abstract

Trifluorovinylsulfur pentafluoride dimerizes to (SF5CFCF2)2 in the presence of cesium fluoride. Two derivatives of trifluorovinylsulfur pentafluoride, SF5CF(CF3)C(O)F and SF5CF(CF3)C(O)NH2, were used to prepare the new compounds, SF5CF(CF3)CO2H and SF5CF(CF3)CN, respectively. The first was prepared by reacting the SF5-acid fluoride with water, while the second involved the abstraction of water from the SF5-amide using P4O10. The attempted preparation of a bis-pentafluorosulfur ketone and a pentafluorosulfur containing acid anhydride were unsuccessful.

Selected transition and post transition metal chlorides and elements undergo oxidative displacement and oxidative addition reactions with F-(tert-butyl) hypochlorite, (CF3)3COCl, to form new F-(tert-butoxides). Preliminary studies with selected aromatic systems were also carried out.

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Comments

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Persistent Identifier

https://archives.pdx.edu/ds/psu/19151

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