First Advisor

Gary L. Gard

Term of Graduation

Spring 1976

Date of Publication

4-16-1976

Document Type

Thesis

Degree Name

Master of Science (M.S.) in Chemistry

Department

Chemistry

Language

English

Subjects

Chromium oxide fluorides

DOI

10.15760/etd.5923

Physical Description

1 online resource (3, 96 pages)

Abstract

New preparative routes to chromyl fluoride were sought. It was found that chlorine monofluoride reacts with chromium trioxide and chromyl chloride to produce chromyl fluoride. Attempts were made to define a mechanism for the reaction of ClF and Cr03 in light of by-products observed and previous investigations. Carbonyl fluoride and chromium trioxide react to form chromyl fluoride and carbon dioxide. A mechanism was also proposed for this reaction. Chromium trioxide with MoF6 or WF6 reacts to produce chromyl fluoride and the respective oxide tetrafluoride.

Rights

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Comments

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Persistent Identifier

http://archives.pdx.edu/ds/psu/23175

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