Advisor

Gary L. Gard

Date of Award

1976

Document Type

Thesis

Degree Name

Master of Science (M.S.) in Chemistry

Department

Chemistry

Physical Description

1 online resource (106 p.)

Subjects

Chromium oxide fluorides

DOI

10.15760/etd.5923

Abstract

New preparative routes to chromyl fluoride were sought. It was found that chlorine monofluoride reacts with chromium trioxide and chromyl chloride to produce chromyl fluoride. Attempts were made to define a mechanism for the reaction of ClF and Cr03 in light of by-products observed and previous investigations. Carbonyl fluoride and chromium trioxide react to form chromyl fluoride and carbon dioxide. A mechanism was also proposed for this reaction. Chromium trioxide with MoF6 or WF6 to produce chromyl fluoride and the respective oxide tetrafluoride.

Description

If you are the rightful copyright holder of this dissertation or thesis and wish to have it removed from the Open Access Collection, please submit a request to pdxscholar@pdx.edu and include clear identification of the work, preferably with URL

Persistent Identifier

http://archives.pdx.edu/ds/psu/23175

Included in

Chemistry Commons

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